Review on possible gravitational anomalies

This is an updated introductory review of 2 possible gravitational anomalies that has attracted part of the Scientific community: the Allais effect that occur during solar eclipses, and the Pioneer 10 spacecraft anomaly, experimented also by Pioneer 11 and Ulysses spacecrafts. It seems that, to date, no satisfactory conventional explanation exist to these phenomena, and this suggests that possible new physics will be needed to account for them. The main purpose of this review is to announce 3 other new measurements that will be carried on during the 2005 solar eclipses in Panama and Colombia (Apr. 8) and in Portugal (Oct.15).Comment: Published in 'Journal of Physics: Conferences Series of the American Institute of Physics'. Contribution for the VI Mexican School on Gravitation and Mathematical Physics "Approaches to Quantum Gravity" (Playa del Carmen, Quintana Roo, Mexico, Nov. 21-27, 2004). Updates to this information will be posted in http://www.lsc-group.phys.uwm.edu/~xavier.amador/anomalies.htm

On the linear increase of the flux tube thickness near the deconfinement transition

We study the flux tube thickness of a generic Lattice Gauge Theory near the deconfining phase transition. It is well known that the effective string model predicts a logarithmic increase of the flux tube thickness as a function of the interquark distance for any confining LGT at zero temperature. It is perhaps less known that this same model predicts a linear increase in the vicinity of the deconfinement transition. We present a precise derivation of this result and compare it with a set of high precision simulations in the case of the 3d gauge Ising model.Comment: 20 pages, 4 figures, minor changes. Accepted for publication in JHE

Flux tube delocalization at the deconfinement point

We study the behaviour of the flux tube thickness in the vicinity of the deconfinement transition. We show, using effective string methods, that in this regime the square width increases linearly and not logarithmically with the interquark distance. The amplitude of this linear growth is an increasing function of the temperature and diverges as the deconfinement transition is approached from below. These predictions are in good agreement with a set of simulations performed in the 3d gauge Ising model.Comment: 16 pages, 1 figure. Revised version, with an improved discussion of the dimensional reduction approach. Accepted for publication in JHE

Microwave-Assisted Knoevenagel-Doebner Reaction: An Efficient Method for Naturally Occurring Phenolic Acids Synthesis

The common chemical method to synthesize Phenolic Acids (PAs) involves a relatively considerable energy intake. In order to solve this issue, microwave-assisted Knoevenagel-Doebner condensations were developed. Nevertheless, these synthetic procedures prove difficult to reproduce. Herein, we developed and optimized—by using a combination of a Design of Experiment and a standard optimization approach—a reliable procedure that converts naturally occuring p-hydroxybenzaldehydes into the corresponding PAs with conversions of 86–99% and in 85–97% yields

Understanding the Impact of Symmetrical Substitution on the Photodynamics of Sinapate Esters Using Gas-Phase Ultrafast Spectroscopy

Two model biomimetic systems, ethyl sinapate (ES) and its symmetrical analogue, diethyl 2-(4-hydroxy-3,5-dimethoxybenzylidene)malonate (or diethyl sinapate, DES), are stripped to their core fundamentals through gas-phase spectroscopy to understand the underlying photophysics of photothermal materials. Following photoexcitation to the optically bright S1(ππ*) state, DES is found to repopulate the electronic ground state over three orders of magnitude quicker than its non-symmetrical counterpart, ES. Our XMS-CASPT2 calculations shed light on the experimental results, revealing crucial differences in the potential energy surfaces and conical intersection topography between ES and DES. From this work, a peak conical intersection, seen for DES, shows vital importance for the non-radiative ground state recovery of photothermal materials. This fundamental comparative study highlights the potential impact that symmetrical substitution can have on the photodynamics of sinapate esters, providing a blueprint for future advancement in photothermal technology

Experimental and numerical characterization of anisotropic damage evolution of forged Al6061-T6 alloy

AbstractAluminum alloy 6061-T6 (Al-Mg-Si) has been selected as the material of the vessel for the construction of Jules-Horowitz material testing reactor. Fracture mechanism of this alloy has been investigated using mechanical testing of smooth and notched tensile specimens loaded in different directions. A strong anisotropic fracture behavior has been observed. Microstructural studies using tomography and image analysis have shown a presence of anisotropic distributed coarse precipitates which is the key microstructural feature affecting the damage evolution. These observations were complemented by investigations on fractured tensile samples. A damage scenario of anisotropic growth and coalescence of voids is proposed to explain the fracture behavior associated with the distribution of precipitates. A GTN (Gurson-Tvergaard-Needleman) damage model is used to simulate this scenario and to predict damage evolution

A Quantum-Conceptual Explanation of Violations of Expected Utility in Economics

The expected utility hypothesis is one of the building blocks of classical economic theory and founded on Savage's Sure-Thing Principle. It has been put forward, e.g. by situations such as the Allais and Ellsberg paradoxes, that real-life situations can violate Savage's Sure-Thing Principle and hence also expected utility. We analyze how this violation is connected to the presence of the 'disjunction effect' of decision theory and use our earlier study of this effect in concept theory to put forward an explanation of the violation of Savage's Sure-Thing Principle, namely the presence of 'quantum conceptual thought' next to 'classical logical thought' within a double layer structure of human thought during the decision process. Quantum conceptual thought can be modeled mathematically by the quantum mechanical formalism, which we illustrate by modeling the Hawaii problem situation, a well-known example of the disjunction effect, and we show how the dynamics in the Hawaii problem situation is generated by the whole conceptual landscape surrounding the decision situation.Comment: 9 pages, no figure

Conceptualising Higher Education and the Public Good in Ghana, Kenya, Nigeria, and South Africa

Higher education has been the object of policy attention in sub-Saharan Africa in recent years. It has been seen as key to unlocking the potential of the youth bulge, responding to the demands of a growing middle class and to transforming commodities-based economies into knowledge societies (World Bank 2009; Cloete, Maassen & Bailey 2015; Chuks, 2017). Yet despite significant expansions of enrolment – including widening participation by women, major barriers to access exist, reflecting inequalities based on class, gender, geographical location, ethnicity, religion, language and disability (AAI 2015; Morley & Lugg 2009; Morley & Croft, 2011). There are quality challenges in relation to teaching and learning, research, and governance. While some comment on a ’renaissance in African higher education’ (Higgs, 2016), and others on the effects and framings of colonial epistemicides (Nyamnjoh, 2012) key questions abound about relevance and power relations highlighting the need to decolonise the curriculum, structure, organisation and cultures of universities. The student protests in South Africa from 2015 highlighted problems of access and funding, but these are not isolated events. They expose an unresolved colonial legacy in these higher education systems. These processes raise questions not only of the public good relevance of higher education - beyond the obvious advantages conferred on those who manage to go to these institutions – but also of how higher education and its relationship with society may be conceptualised given these contexts (Lebeau and Milla, 2008; Mamdani, 2017). An overarching question is who is defining the public good and how? While many of the above issues are global e.g. universities throughout Latin America, Australasia, Asia and Europe are involved in similar debates and protests, this paper explores the relationship between higher education and the public good in the sub- Saharan African context through a consideration of some connections and disconnections. There appear to be two distinct ways in which higher education and the public good have been conceptualised are discussed. Firstly, higher education can be portrayed as instrumental in shaping a version of the public good where its qualifications, knowledge production, innovation, development of the professional classes, and expertise are perceived to lead to particular manifestations of public good, delineated as economic, social, political or cultural (McMahon 2009; Stiglitz 1999). The key arguments that underpin this conceptual framing speak to different levels of the public good, whether individual and community levels or the provision of ‘global public goods’ (Marginson 2007; 2013; Menashy 2009). However, a contrasting set of arguments portray the relationship between higher education and the public good as an intrinsic one, where the intellectual, physical and cultural experiences enabled through higher education express and enact the public good e.g. prejudice reduction, democratisation, critical thinking, active citizenship (Singh 2001; Calhoun 2006; Leibowitz, 2013; Marginson, 2011; Locatelli, 2017). Important here are considerations of the historical conjuncture that shapes experiences of higher education at a particular time and what these may mean. In considering the connections and disjunctures between these two formulations and the way writings on higher education in contemporary Africa have engaged with this debate, the paper makes an argument for discussing the importance of processes that link instrumental and intrinsic visions of higher education and the public good. The analysis of these from a rigorous review of literature leads to a delineation of some different views of time, space and evaluation. The paper argues that these contestations need to be read contextually. Higher education in sub-Saharan Africa has moved through phases, from the establishment of flagship national universities in the post-independence period for state bureaucracy formation (Teferra, 2017), to the emergence of developmental universities with a commitment to indigenising knowledge and benefiting marginalised populations, through more recent tendencies towards the marketisation of public institutions and the significant growth of the private sector (Assié-Lumumba & CODESRIA 2006; ADEA & AAU 2004; Coleman 1986; Mamdani, 2007; McCowan 2016). Appreciating these contextual factors in shaping the role and functioning of higher education and thus its relationship to the public good is a central theme in our analysis. We suggest that mainstream conceptualisations of higher education and the public good are underpinned by particular understandings of the nature and form of higher education and how knowledge is acquired, developed and disseminated – orientations that may be very far from the reality of highly unequal, socially stratified, and politically complex societies within which higher education is deeply embedded. Thus a reconceptualisation of the public is required by these contexts and some challenge to conceptualisations of the private, given the strong obligations of individuals to extended families, and the sharing of the benefits of higher education amongst their communities of origin. The paper concludes with a consideration of what may be important in conceptualising higher education and the public good in the African context and the value of such thinking for broader debates on the role of higher education

Evolution of defects in titanium grade 2 under Ti2+ion irradiation

The complexity and diversity of microstructure involved in titanium alloysmakeit rather difficult to quantitatively describe defect evolution due to irradiation. This paper focusesondefect evolutions of commercially pure titanium grade 2 under Ti2+ ion irradiation considering the effect of dose (0.6 and 3 dpa), temperature (300°C and 430°C) and flux (15:1 ratio). An irradiation damage profile was predicted using SRIM software to obtain a homogeneous damage on at least 500 nm depth for TEM observations and simulated using JANNUS-Saclay facility. The details regarding the quantification methodologies of the defects from dark field images are provided, as are the origins of the associated uncertainties. In addition to a tangled dislocation network, presence of the -type and -component loops is observed. The latter was scarcely reported in the literature in the case of titanium alloys. At low temperature, the size distribution of the -type dislocation loops remained similar regardless of the dose and flux whereas these parameters have highly influence at 430°C. A widening of the size distribution and an increase of the threshold incubation dose (TID) was noted with the temperature. In the case of the -component loops, it was shown that the nucleation occurred in spite of the 0.6 dpa low dose